Interface and Surface Science Laboratory
Research
Why Surfaces?
Our group investigates fundamental structural, electronic, and chemical surface and interface properties of solid materials.
Surfaces of materials are where the action is! Most chemical and physical processes such as gas-solid interactions, atomic-vapor deposition, corrosion, as well as environmental and technological chemical transformation reactions occur at the surface of a material. Therefore, a better understanding of the interplay between composition, structure and chemical properties are important for optimizing technological processes such as thin film synthesis, heterogeneous catalysis, solid state gas sensing, and photocatalysis. In addition, the formation of interfaces between dissimilar materials -- their structural and electronic properties -- is the basis for most microelectronic devices. Finally, reduced sizes and even dimensions of many nanomaterials results in surface properties to become dominant over bulk properties and consequently surface science studies are more important than ever.
Our group currently has two major thrust areas, which enjoy funding from DOE-BES, NSF, and ONR
Metal-oxide Surfaces
Metal oxides are ubiquitous in environmental processes (most materials are covered by an oxide in earth鈥檚 oxidizing atmosphere) and technological applications. Our research focuses on developing an understanding of the properties of simple oxides (structure, chemical, and electronic) properties, and the role of disorder and defects on these oxide surfaces on their fundamental properties. We also investigate how these properties can be tuned by structural and compositional modifications. In terms of applications we are particularly interested in photocatalysis and solid state gas sensors.
STM false color image of the two-dimensional phase of TiO2 with a reduced band-gap.
Selected recent publications
"" Q. Cuan, J. Tao, X.Q. Gong, M. Batzill Phys. Rev. Lett. 108, 106105 (2012).
"" J.G. Tao, T. Luttrell, M. Batzill Nature Chemistry 3, 296-300 (2011).
"" M. Batzill, Energy and Environ. Sci. 4, 3275-3286 (2011).
"" J.G. Tao, M. Batzill J. Phys. Chem. Lett. 1, 3200 (2010)
Materials Science of Graphene
Graphene, a single atomic layer of carbon (graphite), has exciting electronic properties that make it an interesting potential material for novel electronic devices. In addition, it has shown some promise as gas sensing material and electron 鈥揷ollecting component in photocatalysts. Most of our research focuses on fundamental materials science issues of graphene synthesis (in particular chemical vapor deposition (CVD) growth) and mechanisms and control of interface formation between graphene and dissimilar materials, i.e. formation of heterostructured materials.
Atomically resolved scanning tunneling microscopy image of point defects in graphene grown on Ni(111) substrate.
Selected recent publications
"" M.Batzill, Surf. Sci. Rep. 67, 83-115 (2012).
"" R. Addou, A. Dahal, P. Sutter, M. Batzill Appl. Phys. Lett. 100, 021601 (2012).
"" J. Lahiri, T. Miller, L. Adamska, I.I. Oleynik, M. Batzill Nano Letters 11, 518-522 (2011).
"" J. Lahiri, Y. Lin , P. Bozkurt, I. Oleynik, M. Batzill Nature Nanotechnology 5, 326 - 329 (2010).